Enantioselective Copper-Catalyzed SN2′ Substitution with Grignard Reagents
نویسندگان
چکیده
منابع مشابه
Copper-catalyzed asymmetric allylic substitution with aryl and ethyl Grignard reagents.
Phenyl- and ethyl-magnesium bromides undergo regioselective asymmetric allylic substitution with high enantioselectivity under the catalysis of chiral amidophosphane-copper(I) complexes.
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A catalyst system able to perform highly enantioselective Cu-catalysed allylic alkylations with Grignard reagents is described.
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ژورنال
عنوان ژورنال: Synlett
سال: 2001
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-2001-14626